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Preheat oven to 425 degrees F.
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Pound chicken breasts with meat tenderizer to an even thickness.
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Place chicken breasts in large baking dish.
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In a small bow,l stir together brown sugar, dried basil, oregano, salt, pepper and garlic to create dry rub.
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Drizzle chicken breasts with olive oil.
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Massage dry rub into both sides of chicken breast.
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Add canned tomatoes and onions around the sides of chicken.
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Drizzle balsamic vinegar over chicken and tomatoes.
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Bake for 16 to 20 minutes or until chicken is 160 to 165 degrees. (Will depend upon the thickness of chicken.)
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Sprinkle with shredded mozzarella.
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Broil for 3 to 5 minutes or until cheese is fully melted and bubbly.
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Garnish with fresh basil, if desired.
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Serve immediately.